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CHIVA'SSO, a small city of Piedmont, Northern Italy, situated in a fertile plain on the left bank of the Po, about 15 miles north-east of Turin. It was formerly a place of considerable military importance, but its fortifications were destroyed in 1804 by the French. The lampreys of C. are celebrated throughout Piedmont. It has manufactures of bricks, earthenware, soap, &c., and a trade in the agricultural produce of the district. Pop. about 8000.

CHIVE, or CIVE (Allium schoeno'prasum), a plant of the same genus with the leek and onion (see ALLIUM), a perennial, 1 foot in height, with very small, flat, clustered bulbs, increasing by

its bulbs so as to form a sort of turf. The leaves are tubular, cylindrical-tapering, radical, nearly as long as the almost leafless flowering-stem, which is terminated by a hemispherical, many flowered, not bulbiferous umbel of bluish red, or, more rarely, flesh-coloured flowers. The stamens are included within the perianth. This rather pretty little plant grows wild on the banks of rivers, and in marshy or occasionally flooded places in the middle latitudes of Europe and Asia. It is a rare native of Britain. In some of the mountainous districts of Europe a variety is found, larger and stronger in all its parts, and with flowering-stems more leafy. Chives-the name is generally used in the plural-are commonly cultivated in kitchen-gardens, often as an edging for plots, and are used for flavouring soups and dishes. Their properties are very similar to those of the onion. The part used is the young leaves, which bear repeated cuttings in the season.

CHIZEROTS AND BURINS form one of those peculiar races in France that live isolated in the midst of the rest of the population, and are despised and hated by their neighbours. They live in the arrondissement of Bourg-en-Bresse, in the department of Ain; and the communes of Sermoyer, Arbigny, Boz, and Ozan belong to them. According to tradition, they are descended from the Saracens. Although industrious and prosperous,

they are held in the utmost contempt and detestation by their peasant neighbours, who are often indolent and destitute. They are looked upon as covetous and malicious, and scarcely would the daughter of a small farmer, or well-to-do daylabourer, become the wife of one of them, so that they mostly marry among themselves. From time immemorial, the C. and B. have been field-labourers, cattle-dealers, butchers, &c. Many of them are very good-looking. The young women are handsome, clear-complexioned, with large black eyes. Michel, Histoire des Races Maudites de la France et de l'Espagne (2 vols. Par. 1847).

See

CHLADNI, ERNST FLORENS FRIEDRICH, founder of the science of acoustics, was born at Wittenberg, November 30, 1756. He studied law in his native place, and also in Leipsic, where, in 1782, he was made Doctor of Laws. C. ultimately abandoned juridical studies altogether, devoted his mind to natural science, and, being acquainted with music, was led to observe that the laws of sound were by no means so well established as those of other branches of physics. He therefore began to apply his knowledge of mathematics and physics to acoustics, and travelled for ten years (after 1802) through Germany, Holland, France, Italy, Russia, and Denmark, giving lectures on the subject, which were very successful. He died in Breslau, April 3, 1827.-C.'s writings include, Discoveries concerning the Theory of Sound (1787), Acoustics (1802), New Contributions to Acoustics (1817), and Contributions to Practical Acoustics, with Remarks on the making of Instruments (1822). C. also wrote several essays on meteoric stones.

CHLAMY'PHORUS (Gr. chlamys-bearing; chlamys, a soldier's cloak), a very remarkable genus of mammalia of the order Edentata, ranked by naturalists in the same family with the armadillos, but differing in important respects from them, and from all other known quadrupeds. Only one species is known, C. truncatus, five or six inches long, a

CHLOPICKI-CHLORIMETRY.

native of the interior of Chili, living underground Cracow, and withdrew altogether from public life. like the mole, which it much resembles in its habits, He died at Krzeschowitz, 30th September 1854. and feeding on the same kind of food. Its fore-feet are adapted for digging, although in a different manner from those of the mole. The skull is

destitute of sutures; there are resemblances to the

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osteology of birds in the ribs and their union to the sternum; the hinder part of the body is altogether unlike that of any other known animal, in its terminating quite abruptly, as if cut off almost where its thickness is greatest, or as if the back were suddenly bent down at right angles, the tail not springing from where the line of the back appears to terminate, but far below. The whole upper and hinder parts of the body are covered with a coat of mail, made up of a series of square plates; the under parts and legs are covered with long silky hair. The tail is very peculiar ; it is covered with small scales, is expanded at the tip, and is usually incurved along the belly, but is furnished with such muscles as to suggest the probability of its being employed to throw back the

earth in excavations.

CHLOPICKI, JOSEPH, a Polish general, and Dictator of Poland during the revolution of 1830, was born in Galicia in 1772. He entered the army in 1787, attracted the notice of Kosciusko during the first insurrection of the Poles, and after the storming of Praga, 9th November 1794, when the hopes of the patriots were extinguished for awhile, he passed into the service of the new Cisalpine Republic, and distinguished himself in various battles. In 1806 when Bonaparte called the Poles to arms, C., among others, obeyed, and fought gallantly at Eylau and Friedland. He was subsequently sent by the emperor into Spain, and in 1812 followed him to Russia, taking part in the bloody engagements at Smolensk and Moskwa. After the relics of the invading force had returned, C. left the imperial service, on account of receiving certain slights in the way of his professional advancement. After the taking of Paris by the allies in 1814, he led back to Poland the remains of the Polish troops who had fought under Bonaparte, and was well received by the Emperor Alexander, who made him a general of division. When the second insurrection of the Poles broke out in 1830, C., who foresaw the hopeless nature of the attempt, concealed himself; but the voice of the nation called him forth from his hiding-place, and on the 5th December 1830, he was elected dictator. His moderate views, however, involved him in disputes with the extreme patriotic party, and on the 23d January 1831, he resigned his office; but, to prove his sincerity, he entered the Polish army as a simple soldier, and took part in the murderous battles at Wavre and Grochow. After the suppression of the insurrection, C. went to

CHLO'RAL (C,C1,HO,) is a body formed when anhydrous alcohol is acted upon by dry chlorine gas. It is an oily liquid with a peculiar penetrating

odour.

CHLORANTHA'CEE, a natural order of exogenous plants, closely allied to the peppers; herbaceous and half-shrubby plants, with jointed stems, opposite simple leaves, and minute stipules between them. The flowers are in terminal spikes, and are destitute of calyx and corolla, but have each a small scale or bract. The stamens are lateral; either only one or few, and partly cohering. The ovary is one-celled, immediately crowned with the stigma; the ovule is pendulous; the fruit a drupe or one-seeded berry; the embryo naked, not in a fleshy sac as in the peppers.-The number of known species is small: all of them are tropical, or natives of China and Japan. They are generally aromatic, and some of them, as species of Chloranthus in the East Indies, and of Hedyosmum in the West Indies and South America, are used as antispasmodics, stimulants, stomachics, and tonics. The roots of Chloranthus officinalis and C. brachystachys have been ranked among the most efficacious remedies in fevers and other diseases requiring continual and active stimulants, and instances have occurred of great benefit from their employment during the prevalence of epidemics in Java. C. inconspicuus is the CHU-LAN of the Chinese; its leaves, spikes of flowers, and berries are used by them for imparting a peculiar fragrance to tea. All the teas which have what is called the cowslip flavour owe it to this plant.

CHLO'RIC ACID (CIO) is a compound of one atom of chlorine and five atoms of oxygen, and is generally met with in combination with potash, as the white crystalline salt, chlorate of potash (KO,CIO). This salt is mainly interesting from the readiness with which it parts with its oxygen to combustibles, as when thrown on red-hot charcoal, when it causes violent deflagration. The salt is employed in the fabrication of certain kinds of lucifer-matches, which give a slight explosion when struck. If a crystal of chlorate of potash be placed on a piece of paper saturated with turpentine, and a drop or two of oil of vitriol added, it causes the inflaming of the turpentine with explosive rapidity. The chlorate of potash is also used in medicine, with the view of imparting oxygen to the blood.

CHLORIMETRY, or CHLORO'METRY, is the process of estimating the proportion of available chlorine in bleaching powder (q. v.), which may vary from 20 to 36 per cent. The process depends upon the great power with which chlorine, in the act of being liberated from its compounds, causes the oxidation of many substances. The salt generally used is pure crystallised sulphate of iron, which, in its ordinary state, gives a deep blue colour, with a drop of ferridcyanide of potassium, but ceases to do so when it has been fully oxidised, or converted from a proto-salt into a per-salt, through the influence of chlorine. It being known that 78 grains or parts of sulphate of iron are oxidised by 10 grains or parts of chlorine, the mode of procedure in C. is as follows: 78 grains of fine crystals of the sulphate of iron are dissolved in water slightly acidulated with hydrochloric acid in a white porcelain basin. A given quantity of the bleaching powder-say 50 grains-is dissolved in a little tepid water, and introduced into a tall measure-glass called a chlorimeter or burette (figs. 1, 2, and 3), similar to an alkalimeter, which is divided

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CHLORINE-CHLOROFORM.

into 100 parts, and water added till the solution powerful disinfectant (q. v.). The gas can be conrises to the top mark. densed by pressure and cold into a transparent dark greenish-yellow limpid liquid, with a specific gravity of 1330 (HO = 1000), which also possesses bleaching properties, and a most powerful odour. On the animal system C. acts, in very minute quantity, by producing a sensation of warmth in the respiratory passages, and increasing the expectoration; in large quantity, by causing spasm of the glottis, violent cough, and a feeling of suffocation. The workmen in chemical manufactories, who get accustomed to the C. in small quantity, are generally stout-at least, lay on fat-but complain of acidity in the stomach, which they correct by taking chalk, and also suffer from the corrosion of their teeth, which are eaten away to stumps. The antidotes to the evil effects of the introduction of C. into the lungs are the inhalation of the vapour of water, alcohol, ether, or chloroform; but the two latter should never be resorted to except under medical supervision.

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40

40

After subsidence of the insoluble matter, the clear solution is very gradually poured into the solution of sulphate of iron in the basin, the whole being kept cono stantly stirred, and every now and again a drop of 20 the iron solution is taken 30 out and placed on a new drop of ferridcyanide of potassium placed on a 50 white plate; and whenever the iron solution 60 ceases to produce a deep 70 blue, and only forms a light greenish-yellow tint, it is known that the iron 90 has been fully oxidised by the chlorine. Suppose that at this stage the burette has been emptied to the 55th division; as we know that the liquid poured out must have contained 10 grains of chlorine, we can calculate the chlorine contained in the whole; for

50

10

10

120

30

40

50

60

60

170

70

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Thus 50 grains of the powder contain 1818 grains of chlorine, or 36 36 per cent. Protochloride of manganese, subchloride of mercury (calomel), or a solution of indigo of known strength, may be employed instead of the sulphate of iron; but the latter is preferable, and is generally employed by chemists and manufacturers.

CHLORINE (Gr. chloros, pale green) is a nonmetallic element discovered by Scheele in 1774, and named by him dephlogisticated marine air. Afterwards, in 1810, Davy proved it to be an elementary body, and gave it the name which it now bears. In nature it is always found in a state of combination. United with sodium (Na), it occurs very largely as the chloride of sodium (NaCl)-common salt in the ocean; in large beds, as rock-salt; in all natural waters, including even rain-water; in clays, soils, limestone; in volcanic incrustations; and in the vegetable and animal kingdoms. The preparation of gaseous C. by its liberation, directly or indirectly, from common salt, has been fully described under BLEACHING POWDER, which is the form in which C. is prepared and employed commercially. For experimental purposes, the gas may be received in jars filled with water at the pneumatic trough, when the C. rises into the jar, and displaces the water. When thus obtained, it is a yellowish-green gas with a peculiar and suffocating odour, is not combustible, and a very feeble supporter of ordinary combustion. A lighted candle placed in it burns with a very smoky flame, owing to the hydrogen of the oil alone burning, and the carbon being liberated. Several of the metals, such as antimony, copper, and arsenic, in a fine state of division, or in the condition of thin leaves, at once become red hot, and burn when introduced into the gas. A piece of thin paper soaked in turpentine likewise bursts into flame. C. has the symbol Cl, and the atomic weight or equivalent of 355. It is a very heavy gas, nearly 2 times heavier than air, its specific gravity being 2470 (air 1000); it is soluble in cold water to the extent of two volumes of C. in one of water, and yields a solution resembling the gas in colour, odour, and other properties. The principal properties of C. are those of a bleacher of cotton and linen (see BLEACHING), and a most

C. unites with the metals and many other substances to form an extensive class of salts known as chlorides.

CHLO'RITE (Gr. chloros, green), an abundant mineral, consisting of silica, alumina, magnesia, and protoxide of iron, in somewhat variable proportions. It is of a green colour, rarely occurs crystallised in hexagonal crystals, sometimes foliated like talc. It is rather soft, and is easily broken or scratched with a knife. Before the blowpipe, it is with difficulty fused on thin edges. It is readily distinguished from tale by yielding water in a closed tube.

CHLO'RITE-SCHIST, or CHLORITE-SLATE, a green slaty rock, in which chlorite is abundant in foliated plates, usually blended with minute grains of quartz, and sometimes with felspar or mica. It belongs to the metamorphic rocks, and is often found graduating into gneiss and clay-slate.

CHLO'ROFORM, or the TERCHLORIDE OF FO'RMYLE (C,HC13), was originally discovered by Soubeiran, and experimented upon by Dumas, and was long known only to scientific chemists as a rare organic body, possessing interest from being one of a series of organic substances, but not known to possess any properties likely to call it into use, or even likely to let it be known by name to the general public. The remarkable power, however, which it possesses of producing anesthesia, has led to the preparation of C. on a very extensive scale. The materials employed are alcohol, water, and bleaching powder, and the proportions are four parts of bleaching powder, to which sufficient water is added to make a thin paste, and thereafter one part of spirits of wine; the whole is introduced into a capacious retort, which must not be more than half filled, and heat being applied, the C., accompanied by water and a little alcohol, distils over. As the C. is heavier than water, and is not readily miscible therewith, two layers of liquid are obtained in the receiver-the upper being water and alcohol, and the lower being chloroform. The upper liquid being cautiously poured off, the C. is agitated with fused carbonate of potash, which abstracts the remaining traces of water, and on subsequent redistillation the C. is obtained pure and ready for use.

C. is a highly limpid, mobile, colourless liquid, which is very volatile, has a characteristic and pleasant odour, and an agreeable sweetish taste. It has a specific gravity of nearly 1500 (water = 1000), being thus half as heavy again as water, and boils at 140° F. It is not inflammable in the ordinary sense of the term, as it will not take fire

CHLOPICKI-CHLORIMETRY.

native of the interior of Chili, living underground like the mole, which it much resembles in its habits, and feeding on the same kind of food. Its fore-feet are adapted for digging, although in a different

manner from those of the mole.

The skull is

destitute of sutures; there are resemblances to the

Chlamyphorus.

osteology of birds in the ribs and their union to the sternum; the hinder part of the body is altogether unlike that of any other known animal, in its terminating quite abruptly, as if cut off almost where its thickness is greatest, or as if the back were suddenly bent down at right angles, the tail not springing from where the line of the back appears to terminate, but far below. The whole upper and hinder parts of the body are covered with a coat of mail, made up of a series of square plates; the under parts and legs are covered with long silky hair. The tail is very peculiar ; it is covered with small scales, is expanded at the tip, and is usually incurved along the belly, but is furnished with such muscles as to suggest the probability of its being employed to throw back the

earth in excavations.

Cracow, and withdrew altogether from public life. He died at Krzeschowitz, 30th September 1854. CHLO'RAL (C,C1,HO,) is a body formed when anhydrous alcohol is acted upon by dry chlorine gas. It is an oily liquid with a peculiar penetrating

odour.

natural order of

CHLORANTHA'CEÆ, a exogenons plants, closely allied to the peppers; herbaceous and half-shrubby plants, with jointed stems, opposite simple leaves, and minute stipules between them. The flowers are in terminal spikes, and are destitute of calyx and corolla, but have each a small scale or bract. The stamens are lateral; The either only one or few, and partly cohering. ovary is one-celled, immediately crowned with the stigma; the ovule is pendulous; the fruit a drupe or one-seeded berry; the embryo naked, not in a fleshy sac as in the peppers.-The number of known species is small: all of them are tropical, or natives of China and Japan. They are generally aromatic, and some of them, as species of Chloranthus in the East Indies, and of Hedyosmum in the West Indies and South America, are used as antispasmodics, The roots of stimulants, stomachics, and tonics. Chloranthus officinalis and C. brachystachys have been ranked among the most efficacious remedies in fevers and other diseases requiring continual and active stimulants, and instances have occurred of great benefit from their employment during the prevalence of epidemics in Java. C. inconspicuus is the CHU-LAN of the Chinese; its leaves, spikes of All the teas which flowers, and berries are used by them for imparting a peculiar fragrance to tea. have what is called the cowslip flavour owe it to this plant.

CHLO'RIC ACID (CIO) is a compound of one atom of chlorine and five atoms of oxygen, and is generally met with in combination with potash, as the white crystalline salt, chlorate of potash (KO,CIO,). This salt is mainly interesting from the readiness with which it parts with its oxygen to combustibles, as when thrown on red-hot charcoal, when it causes violent deflagration. The salt is employed in the fabrication of certain kinds of lucifer-matches, which give a slight explosion when struck. If a crystal of chlorate of potash be placed on a piece of paper saturated with turpentine, and a drop or two of oil of vitriol added, it causes the inflaming of the turpentine with explosive rapidity. The chlorate of potash is also used in medicine, with the view of imparting oxygen to the blood.

CHLOPICKI, JOSEPH, a Polish general, and Dictator of Poland during the revolution of 1830, was born in Galicia in 1772. He entered the army in 1787, attracted the notice of Kosciusko during the first insurrection of the Poles, and after the storming of Praga, 9th November 1794, when the hopes of the patriots were extinguished for awhile, he passed into the service of the new Cisalpine Republic, and distinguished himself in various battles. In 1806 when Bonaparte called the Poles to arms, C., among others, obeyed, and fought gallantly at CHLORIMETRY, or CHLORO'METRY, is Eylau and Friedland. He was subsequently sent by the emperor into Spain, and in 1812 followed him the process of estimating the proportion of available to Russia, taking part in the bloody engagements chlorine in bleaching powder (q. v.), which may at Smolensk and Moskwa. After the relics of the vary from 20 to 36 per cent. The process depends invading force had returned, C. left the imperial upon the great power with which chlorine, in the service, on account of receiving certain slights in act of being liberated from its compounds, causes After the oxidation of many substances. The salt genethe way of his professional advancement. the taking of Paris by the allies in 1814, he led back rally used is pure crystallised sulphate of iron, to Poland the remains of the Polish troops who had which, in its ordinary state, gives a deep blue fought under Bonaparte, and was well received by colour, with a drop of ferridcyanide of potassium, the Emperor Alexander, who made him a general of but ceases to do so when it has been fully oxidised, division. When the second insurrection of the or converted from a proto-salt into a per-salt, Poles broke out in 1830, C., who foresaw the hope- through the influence of chlorine. It being known less nature of the attempt, concealed himself; but that 78 grains or parts of sulphate of iron are the voice of the nation called him forth from his oxidised by 10 grains or parts of chlorine, the mode hiding-place, and on the 5th December 1830, he was of procedure in C. is as follows: 78 grains of elected dictator. His moderate views, however, fine crystals of the sulphate of iron are dissolved involved him in disputes with the extreme patriotic in water slightly acidulated with hydrochloric acid party, and on the 23d January 1831, he resigned his in a white porcelain basin. A given quantif office; but, to prove his sincerity, he entered the the bleaching powder-say 50 g Polish army as a simple soldier, and took part in in a little tepid water, and in the murderous battles at Wavre and Grochow. measure-glass called a chlorim After the suppression of the insurrection, C. went to 2, and 3), similar to an al

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